Characterization of Combinatorial Polymer Blend Composition Gradients by FTIR Microspectroscopy
نویسندگان
چکیده
A new FTIR technique was developed for characterizing thin polymer films used in combinatorial materials science. Fourier transform infrared microspectroscopy mapping technique was used to determine the composition of polymer blend gradients. Composition gradients were made from poly(L-lactic acid) (PLLA) and poly(D,L-lactic acid) (PDLLA) in the form of thin films (6 cm × 2 cm) deposited on IR reflective substrates. Three composition gradient films were prepared and characterized. The results demonstrate the reproducibility and feasibility of a new, high-throughput approach for preparing and characterizing polymer composition gradients. The combination of composition gradient film technology and automated nondestructive FTIR microspectroscopy makes it possible to rapidly and quantitatively characterize polymer composition gradients for use in combinatorial materials science.
منابع مشابه
Combinatorial/high throughput methods for the determination of polyanhydride phase behavior.
Combinatorial methods have been developed to study the phase behavior of biodegradable polyanhydrides for drug delivery applications. The polyanhydrides of interest are poly[1,6-bis(p-carboxyphenoxy) hexane] (CPH) and poly[sebacic anhydride] (SA). Both continuous and discrete polymer blend libraries were fabricated by using a combination of solution-based gradient deposition and rapid prototypi...
متن کاملFTIR Microspectroscopy of Polymeric Systems
Fourier transform infrared (FTIR) spectroscopy is a mature analytical technique employed to examine polymeric materials. With the coupling of an infrared interferometer to a microscope equipped with specialized detectors, FTIR spectroscopy has been employed widely to examine microscopic areas in polymers for the last twenty years. Following the emergence of instrumentation techniques that emplo...
متن کاملPreparation and Characterization of PVDF/PMMA/Graphene Polymer Blend Nanocomposites by Using ATR-FTIR Technique
متن کامل
Preparation and characterization of lithium ion conducting polymer electrolytes based on a blend of poly(vinylidene fluoride-co-hexafluoropropylene) and poly(methyl methacrylate)
Ion conducting polymer electrolytes composed of poly(vinylidene fluoride-co-hexafluoropropylene) (PVdF-HFP), poly(methyl methacrylate) (PMMA) and lithium triflate (LiTf) were prepared using the solution casting method. Structural change and complex formation in the blend electrolyte systems were confirmed from the X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy and scann...
متن کاملFabrication and Characterization of Polymer Blend Doped With Metal Carbide Nanoparticles for Humidity Sensors
Nanocomposites films of (polymer blend-ceramics) were prepared from (PVA-PAA) blend and (PVA-PAA) blend doped with niobium carbide nanoparticles for humidity sensors have low cost, easy fabrication, high sensitivity, lightweight and high corrosion resistance. The structural, electrical and optical properties of (PVA-PAA-NbC) nanocomposites have been studied. The D.C electrical properties of (PV...
متن کامل